水解酸化-深井曝气-脱气-二沉池工艺处理印染废水工程实例

对某纺织企业污水站进行改造,由于用地紧张,将污水站生物接触氧化工艺改造成深井曝气工艺,大大节约了土地资源,并且有较好的处理效果。深井曝气具有抗冲击能力强、氧利用率高、管理方便、运行稳定、低能耗、占地省等优点,因此越来越多的被应用到印染纺织废水的处理中。但也存在着缺点:污泥龄比较短,硝化效果比较差,导致脱氮能力不强,污泥的稳定程度比低负荷工艺低,钻井技术要求也相对较高等。总之,深井曝气工艺是一种先进的处理工业废水的新工艺,若能扬长避短,将会得到广泛应用。     

袋式除尘器清灰后除尘空间浓度场分析

通过动量守恒方程建立袋式除尘器滤袋清灰后滤袋周围浓度场的数学模型,并应用该模型分别对粗细粉尘,通过改变气流上升速度、袋间距,来计算除尘空间浓度场随时间的变化。结果表明:较细的颗粒物基本悬浮在袋口下0.5～2.5 m(滤袋长度8.3%～41.7%)的除尘空间中,而较粗的颗粒物沉积到滤袋的中下部被过滤;袋间距越小,其过滤浓度越大,相应的过滤速度也比较大;随着上升速度的增大,粒子悬浮的空间离袋口越近,其平均浓度也相应的越低(重新被过滤的颗粒物也越多)。     

云南电网防范自然灾害风险预警系统设计

为了防范自然灾害对云南电网所产生的危害,笔者在收集处理相关数据后建立了防范自然灾害的模型,并根据受灾模型、风险评估模型等建立了数据库,通过GIS软件设计出风险预警系统。本文重点从重大地质灾害风险点的监测预警解决方案、基于气象降雨量的地质灾害预警解决方案、软件系统功能模块、软件系统特点等方面进行分析与设计该系统。     

安全带整体静负荷试验机的研制及应用

安全带是有效地预防高处作业人员因意外坠落而受到身体伤害的必要防护装备。本文根据GB6095—2009《安全带》、GB／T6096—2009《安全带测试方法》标准中安全带整体静态负荷试验的要求,对安全带整体静负荷试验机的研制与应用开展一些调研和探讨,希望对从事安全带检验的机构和安全带生产的企业中的科研、检验人员提供一些感性的认知和帮助。     

溴化十四烷基吡啶对膨润土吸附萘的增强效应及机理

研究了溴化十四烷基吡啶(MPB)对膨润土吸附萘的增强效应、机理及影响因素,试图为有机膨润土在污染环境修复中的应用提供新的技术路线.结果表明,MPB能显著增强膨润土对萘的吸附作用,增强效应及机理与MPB浓度有关.当MPB平衡浓度(X)在0～1/10CMC之间,MPB几乎全部被膨润土吸附,对萘产生分配作用,其表观分配系数(K_d^*)随MPB加入量的增大而急剧增大;当X在1/10CMC～ICMC之间,由于表面活性剂的吸附作用及其单体的增溶作用,K_d^*值则缓慢减小;当X大于1CMC,由于增加的表面活性剂主要起胶束增溶作用,K_d^*值则急剧减小.引入了标化表观分配系数(K_oc^*)探讨萘在表面活性剂-膨润土-水体系中的吸附机理,其倒数(1/K_oc^*)与X呈线性关系;由线性斜率和截距可求得K_oc、K_mn、K_mc参数.     

稻田层间流活性磷素的动态变化

采用特氟纶管采样法,原位、动态、实时地研究了水田15～20cm层间流活性磷(钼酸盐反应磷,MRP)的流失浓度及潜能.研究表明,早稻生长期间水田层间流MRP浓度为0.110～0.273 mg/L,晚稻生长期的MRP浓度为0.085～0.285 mg/L;水田15～20cm层间流磷素浓度差异与施用磷肥造成的土壤含磷水平大小直接相关,且随着土壤磷素的提高其流失潜能随之增加;配施有机肥不影响水田层间流磷素的流失潜能.     

北京地区地表水中OCPs和PCBs的污染分析

在夏、冬两季对北京地区密云,潮白河,玉渊潭和通惠河等地表水中17种有机氯农药（OCPs）和84种多氯联苯（PCBs）的含量进行了分析及来源解析.实验结果表明,OCPs总量在7.86～53.1ng/L之间,平均值为（16.9±14.6）ng/L.PCBs总量在2.99～32.7ng/L之间,平均浓度为（10.9±10.4）ng/L.HCHs,硫丹,DDTs和HCB是主要的OCPs污染物,其含量分别为（13.9±11.5）ng/L,（2.20±2.01）ng/L,（0.63±1.51）ng/L和（0.12±0.14）ng/L.α-HCH/γ-HCH平均比值为1.53,小于工业HCH中比值4～7,表明北京地区地表水中存在林丹的使用.而DDT/（DDD+DDE）比值<1.22,表明北京地区并无新的DDTs污染源输入环境.PCBs以低氯代联苯为主,其中二氯,三氯,四氯和五氯联苯总和占∑₈₄PCBs总量的79.2%.北京地区地表水中不同氯取代数PCBs组成与我国历史PCB产品组成相符,均以低氯代联苯为主,表明北京地区地表水中PCBs污染来源为历史使用.相比于国内其他区域水质而言,北京地区地表水OCPs和PCBs污染水平较低.     

Investigation of correlativity between heavy metals concentration in indigenous plants and combined pollution soils

The accumulation of heavy metals (HMs) in soils is potentially hazardous to human, livestock and plant species. HMs in the combined pollution soils and indigenous plants were investigated in a non-ferrous metal-smelting area. The purpose of this study was to determine the HMs in the contaminated soil and different plant species found growing on it, as well as calculation of bioaccumulation coefficients (BACs). Representative sampling sites were identified according to the land-use types. A total of 12 surface soil samples and 32 plant samples were collected. HMs were analysed by inductively coupled plasma mass spectrometry. The levels of soil pollution were assessed using Nemerow’s synthetical contamination index method. The synthetical index was in the range of 16.81–198.11. This result indicated a heavy burden on local environment. HM concentrations in plants were directly related with soil concentrations. The average BACs of five metals were found in the order of Cd (0.309)?>?Zn (0.178)?≈?Pb (0.160)?>?Cu (0.105)?>?Sb (0.0672). Spontaneous weeds including Chenopodium album Linn, Kochia scoparia and trees of Leuce, Ulmus pumila were deemed HM accumulators. The results provided a practical basis for phytoremediation of HM-contaminated soils using accumulator species.     

New insights into FeS/persulfate system for tetracycline elimination: Iron valence, homogeneous-heterogeneous reactions and degradation pathways

In this study, complete tetracycline（TTC） and above 50% of total organic carbon（TOC） were removed by Fe S/PS after 30 min under optimized conditions. Although free radicals and high-valent iron ions were identified to generate in the process, the apparent similarity between intermediate products of Fe S/PS, Fe/PS, and UV/PS systems demonstrated that the degradation of TTC was due to sulfate radicals(SO₄^·-) and hydroxyl radicals（ ·OH）. Based on the reaction between free radi...     

Evaluation on exposures to particulate matter at a junior secondary school: a comprehensive study on health risks and effective inflammatory responses in Northwestern China

Air pollutant measurement and respiratory inflammatory tests were conducted at a junior secondary school in Xi’an, Northwestern China. Hazardous substances including particulate matters (PMs), black carbon (BC) and particle-bounded polycyclic aromatic hydrocarbons (PAHs) were quantified both indoors and outdoors of the school. Source characterization with organic tracers and particle-size distribution demonstrated that the school’s air was mostly polluted by combustion emissions from the surrounding environment. The evaluation of health assessment related to air quality was conducted by two methods, including potential risk estimation of air pollutants and direct respiratory inflammatory test. The incremental lifetime cancer risks associated with PAHs were estimated and were 1.62 × 10⁻⁶ and 2.34 × 10⁻⁶, respectively, for indoor and outdoor fine PMs. Both the values exceeded the threshold value of 1 × 10⁻⁶, demonstrating that the carcinogenic PAHs are a health threat to the students. Respiratory inflammatory responses of 50 students who studied in the sample classroom were examined with a fractional exhaled nitric oxide (FeNO) test, with the aid of health questionnaires. The average FeNO concentration was 17.4 ± 8.5 ppb, which was slightly lower than the recommended level of 20 ppb established by the American Thoracic Society for children. However, a wide distribution and 6% of the values were > 35 ppb, suggesting that the potentials were still high for eosinophilic inflammation and responsiveness to corticosteroids. A preliminary interpretation of the relationship between air toxins and respiratory inflammatory response demonstrated the high exposure cancer risks and inflammatory responses of the students to PMs in the city.